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Energy levels and transition rates for the boron isoelectronic sequence: Si X, Ti XVIII – Cu XXV

机译:硼等电子序列的能级和转变率:si X,Ti XVIII-Cu XXV

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摘要

Relativistic configuration interaction (RCI) calculations are performed for 291 states belonging to the configurations 1s22s22p,1s22s2p2, 1s22p3, 1s22s23l, 1s22s2p3l, 1s22p23l, 1s22s24l , 1s22s2p4l , and 1s22p24l (l = 0, 1,2 and l = 0, 1, 2, 3) in boron-likeions Si X and Ti XVIII to Cu XXV. Electron correlation effects are represented in the wave functions by large configuration statefunction (CSF) expansions. States are transformed from j j-coupling to LS -coupling, and the LS -percentage compositions are usedfor labeling the levels. Radiative electric dipole transition rates are given for all ions, leading to massive data sets. Calculated energylevels are compared with other theoretical predictions and crosschecked against the Chianti database, NIST recommended values, andother observations. The accuracy of the calculations are high enough to facilitate the identification of observed spectral lines.
机译:对属于配置1s22s22p,1s22s2p2、1s22p3、1s22s23l,1s22s2p3l,1s22p23l,1s22s24l,1s22s2p4l和1s22p24l的291个状态执行相对论配置交互(RCI)计算(l = 0、1、2和1 ,3)硼样Si X和Ti XVIII到Cu XXV。电子相关效应在波函数中由大的组态状态函数(CSF)展开表示。将状态从j j耦合转换为LS耦合,并且使用LS百分比组成标记水平。给出了所有离子的辐射电偶极跃迁速率,从而产生了大量数据集。将计算出的能级与其他理论预测值进行比较,并根据Chianti数据库,NIST建议值和其他观察结果进行交叉核对。计算的准确性足够高,可以帮助识别观察到的谱线。

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